JIANG Xue-jun, YAO De, LIN Xue-hui, ZHAI Shi-kui. GEOCHEMISTRY OF CU, CO, NI, TI,AND MG IN DIAGENETIC FERROMANGANESE NODULES[J]. Marine Geology & Quaternary Geology, 2007, 27(6): 47-54.
Citation: JIANG Xue-jun, YAO De, LIN Xue-hui, ZHAI Shi-kui. GEOCHEMISTRY OF CU, CO, NI, TI,AND MG IN DIAGENETIC FERROMANGANESE NODULES[J]. Marine Geology & Quaternary Geology, 2007, 27(6): 47-54.
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GEOCHEMISTRY OF CU, CO, NI, TI,AND MG IN DIAGENETIC FERROMANGANESE NODULES

  • 1 College of Geoscience, Ocean University of China, Qingdao 266100, China;

  • 2 Qingdao Institute of Marine Geology, Qingdao 266071, China;

  • 3 Shandong University of Technology, Zibo 255049, China

More Information
  • Received Date: June 25, 2007
  • Revised Date: November 01, 2007
    Graphical Abstract
    • Abstract
  • A series of selective dissolution experiments were conducted on the diagenetic ferromanganese nodules from the East Pacific Ocean near the equator to study the geochemistry of Cu, Co, Ni, Ti,and Mg. Enrichments of the elements are controlled by the present states of the elements in the seawater and the compositional minerals of the ferromanganese deposits. The stability of the structure of 10Å-manganates in diagenetic nodules is attributed to the alkali earth element Mg in the structure besides the transitional metal elements Cu, Co and Ni incorporated into the structure that can stabilize the structure of 10Å-manganates.
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    • References (20)
  • [1]
    Craig J D, Andrews J E, Meylan M A. Ferromanganese deposits in the Hawaiian Archipelago[J]. Mar. Geol., 1982,45:127-157.
    [2]
    Taematsu N, Sato Y, Okabe S. Factors controlling the chemical composition of marine manganese nodules and crusts:a review and synthesis[J]. Mar. Chem., 1989, 26:41-56.
    [3]
    Yoshikawa K. The relationship between manganese minerals and metallic elements in deep-sea manganese nodules[J]. Mar. Geol., 1991, 101:267-286.
    [4]
    Lei Guo-Bin, Bostrom B K. Mineralogical control on the transition metal distributions in marine manganese nodules[J]. Mar. Geol., 1995,123:253-261.
    [5]
    Usui A, mellin T, Nohara M, et al. Structural stability of marine 10Å manganates from the Ogasawara(Bonin) Arc:Implications for low-temperature hydrothemal activity[J]. Mar. Geol., 1989,86:41-56.
    [6]
    Matin-Barajas A, Lallier-Verges E, Leclaire L. Characteristics of manganese nodules from the Central Indian Basin:Relationship with the sedimentary environment[J]. Mar. Geol., 1991,101:249-265.
    [7]
    Mellin T A, LEI Guo-Bin. Stabilization of 10Å -manganates by interclayerc ations and hydrothermal treatment:Implications for the mineralogy of marine manganese concretions[J]. Mar. Geol., 1993,115:67-83.
    [8]
    许东禹. 多金属结核的特征及成因[M]. 北京:地质出版社, 1993:32.[XU Dong-yu. The origin and characteristics of polymetallic nodules in the Central Pacific Ocean[M]. Beijing:Geological Publishing House,1993:32]
    [9]
    Usui A, Nishimura A, Mita A. Composition and growth history of surficial and buried manganese nodules in the Penrhyn Basin, Southwestern Pacific[J].Mar. Geol., 1993,114:133-153.
    [10]
    Koschinsky A,Halbach P.Sequential leaching of marine ferromanganese precipitates:Genetic implications[J]. Gechimica et Cosmochimica Acta,1995,59:5113-5132.
    [11]
    Chen X, Cheng H,Ma J.A study on the stability and rheological behavior of concentrated TiO2 dispersions[J]. Powder Technol.,1998,99:171-176.
    [12]
    Venz P A, Frost R L,Kloprogge J T.Chemical properties of modified titania hydrolysates[J]. J. Non-Cryst. Solids,2000,276, 95-112.
    [13]
    Stumm W,Morgan J J.Aquatic Chemistry, 2nd ed[M].John Wiley & Sons, Inc.,1981:442-502.
    [14]
    LEI Guo-Bin. Crystal structure and metal uptake capacity of 10Å-manganates:An overview[J]. Mar. Geol., 1996,133:103-112.
    [16]
    陈冠球.多金属结核主要元素的地球化学行为[M].北京:地质出版社,1994.[CHEN Guan-qiu. Geochemical behavior of major elements in polymetallic nodules[M]. Beijing:Geological Publishing House,1994.]
    [17]
    Dillard J G, Crowther D L. The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules[J]. Geochim. Cosmochim. Acta, 1982, 46:755-759.
    [18]
    Burns R G. The uptake of cobalt into ferromanganese nodules, soils, and synthetics manganese(IV) oxides[J]. Geochim. Cosmochim. Acta, 1976,40:95-102.
    [19]
    White W M.Geochemistry:Chapter 15:The Oceans as a Chemical System[M]. John-Hopkins University Press,1998.
    [20]
    Shen Y F, Zerger R P, DeGuzman R N,et al.Manganese oxide octahedral molecular sieves:Preparation, characterization, and applications[J]. Science, 1993,260:511-515.
    [21]
    Usui A.Nickel and copper accumulation as essential elements in 10Å -manganite of deep-sea manganese nodules[J]. Nature, 1979,279:411-413.
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