ZOU Liang, WEI Gang-jian. DISTRIBUTION OF MAJOR ELEMENTS IN SEDIMENT BY SEQUENTIAL EXTRACTION PROCEDURES[J]. Marine Geology & Quaternary Geology, 2007, 27(2): 133-140.
Citation: ZOU Liang, WEI Gang-jian. DISTRIBUTION OF MAJOR ELEMENTS IN SEDIMENT BY SEQUENTIAL EXTRACTION PROCEDURES[J]. Marine Geology & Quaternary Geology, 2007, 27(2): 133-140.

DISTRIBUTION OF MAJOR ELEMENTS IN SEDIMENT BY SEQUENTIAL EXTRACTION PROCEDURES

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  • Received Date: November 14, 2006
  • Revised Date: January 04, 2007
  • Distribution of major elements in marine sediments and water system was studied in this paper by using a modified sequential extraction procedure according to the methods of Tessier,BCR and so on. Concentrations of Ti,Al,Na,Mg,K,Ca,P,Fe,and Mn in the extracted components leached by different reagents were measured using inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES). The results indicate that the most abundant elements extracted by water are Na and Ca, and Ca and P tend to be abundant in organic materials compared with other elements. Large amounts of Ca and Mg are extracted by HAc, which may result from dissolution of carbonate. Additionally, some of the Al, Mn, Na and K are also extracted by HAc. In the component extracted by diluted HCl, the concentrations of these elements except Ti are high, indicating that authigenic materials were significantly dissolved. However, nearly all the Ti in sediments retains in the residue after previous four extraction procedures, suggesting that Ti is mostly hosted in detrital component. The Ti-normalized ratios of other elements in the extracted components all show significantly higher values than those of the average composition in sediments in China, indicating that the dissolved components are mainly authigenic biogenic materials, and the residue after this sequential extraction can basically represent the terrestrial detrital component in sediments.
  • [1]
    韦刚健,刘颖,邵磊,等. 南海碎屑沉积物化学组成的气候记录[J]. 海洋地质与第四纪地质,2003,23(3):1-4.

    [WEI Gang-jian, LIU Ying, SHAO Lei, et al. Climatic records in the major elements of the terrestrial detritus from the South China Sea[J]. Marine Geology and Quaternary Geology, 2003,23(3):1-4.]
    [2]
    杨守业,Jung Hoi-soo,李从先,等. 黄河、长江与韩国Keum、Yeongsan江沉积物常量元素地球化学特征[J]. 地球化学,2004,33(1):99-105.

    [YANG Shou-ye, Jung Hoi-soo, LI Cong-xian, et al. Major element geochemistry of Chinese and Korean rivers[J]. Geochimica Acta, 2004,33(1):99-105.]
    [3]
    WEI Gang-jian, LIU Ying, LI Xian-hua, et al. Climatic impact on Al, K, Sc and Ti in marine sediments:Evidence from ODP Site 1144, South China Sea[J]. Geochemical Journal, 2003,37(5):593-602.
    [4]
    WEI Gang-jian, LIU Ying, LI Xian-hua, et al. Major and trace element variations of the sediments at ODP Site 1144, South China Sea, during the last 230 ka and their paleoclimate implications[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2004,212(3-4):331-342.
    [5]
    Tessier A, Campbell P G C, Bisson M. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytica Chimica Acta,1979, 51(7):844-851.
    [6]
    Tessier A, Campbell P G C. Comment on "Pitfalls of sequential extractions" by F M M MOREL[J]. Water Research, 1991, 25(1):115-117.
    [7]
    Kryc K A, Murray R W, Murray D W. Elemental fractionation of Si, Al, Ti, Fe, Ca, Mn, P, and Ba in five marine sedimentary reference materials:results from sequential extractions[J]. Analytica Chimica Acta, 2003, 487(1):117-128.
    [8]
    Robbins J M, Lyle M, Heath G R. A sequential extraction procedure for partitioning elements among Co-existing phases in marine sediments[J]. Cosmochim. Acta, 1984,52:2127-2145.
    [9]
    LI Xiang-dong, Coles B J, Ramsey M H, et al. Sequential extraction of soils for multielement analysis by ICP-AES[J]. Chem Geol, 1995,124(2):109-123.
    [10]
    Accuracy of selective extraction procedures for metal speciation in model aquatic sediments[J]. Analytica Chimica Acta, 1987,59:1417-1423.
    [11]
    刘颖,刘海臣,李献华.用ICP-MS准确测定岩石样品中的40余种微量元素[J]. 地球化学, 1996, 25(6):552-558.

    [LIU Ying, LIU Hai-chen, LI Xian-hua. Simultaneous and precise determination of 40 trace elements in rock samples using ICP-MS[J]. Geochimica, 1996, 25(6):552-558.]
    [12]
    李献华,刘颖,涂湘林,等.硅酸盐岩石化学组成的ICP-AES和ICP-MS准确测定:酸溶与碱熔分解样品方法的对比[J]. 地球化学,2002,31(3):289-294.

    [LI Xian-hua, LIU Ying, TU Xiang-lin, et al. Precise determination of chemical compositions in silicate rocks using ICP-AES and ICP-MS:A comparative study of sample digestion techniques of alkali fusion and acid dissolution[J]. Geochimica, 2002, 31(3):289-294.]
    [13]
    CoX R A, Culkin F, Riley J P. The electrical conductivity/chlorinity relationship in natural sea water[J]. Deep Sea Research and Oceanographic Abstracts, 1967,14(2):203-220.
    [14]
    Gabriel M Filippelli,Margaret Lois Delaney. Phosphorus geochemistry of equatorial Pacific sediments[J]. Geochimica et Cosmochimica Acta, 1996,60(9):1479-1495.
    [15]
    Murray R W, Leinen M. Scavenged excess aluminum and its relationship to bulk titanium in biogenic sediment from the central equatorial Pacific Ocean[J]. Geochimica et Cosmochimica Acta, 1996,60(20):3869-3878.
    [16]
    韦刚健,刘颖,李献华,等.南海沉积物中过剩Al问题的探讨[J]. 矿物岩石地球化学通报,2003,22(1):23-25.

    [WEI Gang-jian, LIU Ying, LI Xian-hua,et al. Excess Al in the sediments from South China Sea[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2003,22(1):23-25.]
    [17]
    马金龙,韦刚健,贾国东. 碱提取法分析海洋沉积物生物硅方法中碎屑组分污染的评估及校正[J]. 地球化学,2005,34(3):285-290.

    [MA Jin-long, WEI Gang-jian, JIA Guo-dong. Evaluation and calibration on the detrital contamination to biogenic opal of marine sediments by alkali leachate methods[J]. Geochimica, 2005,34(3):285-290.]
    [18]
    赵一阳,鄢明才.中国浅海沉积物化学元素丰度[J].中国科学B辑,1993,23(10):1084-1090.

    [ZHAO Yi-yang, YAN Ming-cai. The abundant of chemical elements in shallow sea sediment of China[J]. Science in China (Series B), 1993,23(10):1084-1090.]
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