Citation: | ZHAO Zhuxu,XIONG Wei,WANG Zhonglei,et al. Distribution and origination of rare earth elements in surface sediments of the Bohai Strait[J]. Marine Geology & Quaternary Geology,2024,44(5):151-160. DOI: 10.16562/j.cnki.0256-1492.2024072501 |
To understand the material exchange between the Yellow Sea and the Bohai Sea, the distribution and origination of rare earth elements (REE) in surface sediments from 383 stations in the Bohai Strait were studied, the influencing factors, main sources of materials, and migration mechanisms of the REE were analyzed systematically. Results indicate that the total REE content (∑REE) in the sediments of the Bohai Strait ranges from 44.85 to 283.00 μg/g, on average o of 166.33 μg/g. The high-value areas were distributed in mainly the western and southern sea areas with finer sediments, while the low-value areas were located in the northeastern sea areas with coarser sediments, showing characteristics of light REE enrichment and heavy REE depletion. Correlation analysis between ∑REE and certain characteristic parameters to grain size, chemical index of alteration (CIA), and some elements, we found that ∑REE is positively correlated with sediment mean grain size, indicating a close relationship between REE distribution and sediment grain size / provenance. The distribution patterns of REEs in the upper continental crust and chondritic meteorites in the Bohai Strait show similarities with the material carried by the Huanghe (Yellow) River and rivers surrounding the Liaodong Bay, indicating a distinct terrigenous imprint of riverine materials. In contrast, there are significant differences with the Yalu River and rivers in the Korean Peninsula, indicating that the primary source of the material is from the Chinese mainland. Using the standardized calculation of δEu-(La/Yb)N and (Gd/Yb)N-(La/Yb)N indices based on chondritic meteorites, source discrimination was conducted. The results indicate that the material in the Bohai Strait mainly originates from the Huanghe River, while in the northeastern sea areas of the Bohai Strait, it is a mixture of the Huanghe River and rivers surrounding the Liaodong Bay. The combined effect of Liaodong Bay circulation and Bohai Sea coastal current affects the sedimentary patterns in the Bohai Strait.
[1] |
Singh P R. REE geochemistry of recent clastic sediments from the Kaveri floodplains, southern India: Implication to source area weathering and sedimentary processes[J]. Geochimica et Cosmochimica Acta, 2001, 65(18):3093-3108. doi: 10.1016/S0016-7037(01)00636-6
|
[2] |
Lim D, Jung H S, Choi J Y. REE partitioning in riverine sediments around the Yellow Sea and its importance in shelf sediments provenance[J]. Marne Geology, 2014, 357:12-24. doi: 10.1016/j.margeo.2014.07.002
|
[3] |
Jung H, Lim D, Jeong D, et al. Discrimination of sediment provenance in the Yellow Sea: secondary grain-size effect and REE proxy[J]. Journal of Asian Earth Science, 2016, 123:78-84. doi: 10.1016/j.jseaes.2016.03.020
|
[4] |
蒋富清, 李安春. 冲绳海槽南部表层沉积物地球化学特征及其物源和环境指示意义[J]. 沉积学报, 2002, 20(4):680-686 doi: 10.3969/j.issn.1000-0550.2002.04.024
JIANG Fuqing, LI Anchun. Geochemical Characteristics and Their Implications to Provenance and Environment of Surface Sediments from the South Okina wa Trough[J]. Acta Sedimentologica Sinica, 2002, 20(4):680-686.] doi: 10.3969/j.issn.1000-0550.2002.04.024
|
[5] |
Xue C T, Qin Y C, Ye S Y, et al. Evolution of Holocene ebb-tidal clinoform off the Shandong Peninsula on East China Sea shelf[J]. Earth Science Reviews, 2018, 177:478-496. doi: 10.1016/j.earscirev.2017.12.012
|
[6] |
虞义勇, 褚宏宪, 杨慧良, 等. 渤海海峡表层沉积物常量元素分布特征及其地质意义[J]. 海洋地质前沿, 2019, 35(9):52-62
YU Yiyong, CHU Hongxian, YANG Huiliang, et al. Distribution of Major Elements in Surface Sediments of Bohai Strait and Its Geological Significance[J]. Marine Geological Frontiers, 2019, 35(9):52-62.]
|
[7] |
段云莹, 裴绍峰, 廖名稳, 等. 渤海莱州湾沉积物REE与重金属污染特征及物源判别[J]. 海洋地质前沿, 2021, 37(10):8-24
DUAN Yunying, PEI Shaofeng, LIAO Mingwen, et al. Characteristic of REE and Heavy Metals in the Surficial Sediments of Laizhou Bay, Bohai Sea and Their Implications for Provenance[J]. Marine Geological Frontiers, 2021, 37(10):8-24.]
|
[8] |
Martin J M, Zhang J, Shi M C, et al. Actual flux of the Huanghe (Yellow River) sediment to the Western Pacific Ocean[J]. Netherlands Journal of Sea Research, 1993, 31(3):243-254. doi: 10.1016/0077-7579(93)90025-N
|
[9] |
Yang Z, Ji Y, Bi N S, et al. Sediment transport off the Huanghe (Yellow River) delta and in the adjacent Bohai Sea in winter and seasonal comparison[J]. Estuarine coastal and shelf science, 2011, 93(3):173-181. doi: 10.1016/j.ecss.2010.06.005
|
[10] |
Qiao S, Shi X F, Zhu A, et al. Distribution and transport of suspended sediments off the Yellow River (Huanghe) mouth and the nearby Bohai Sea[J]. Estuarine Coastal & Shelf Science, 2010, 86(3):337-344.
|
[11] |
杨娅敏, 张礼中, 沈睿文, 等. 渤海湾唐山港海域表层沉积物粒度和黏土矿物分布特征及其物源指示[J]. 海洋地质与第四纪地质, 2023, 43(5):136-147
YANG Yamin, ZHANG Lizhong, SHEN Ruiwen, et al. Characteristics of grain size and clay mineral distribution of surface sediments and their provenance implication in Tangshan Harbor, Bohai Bay[J]. Marine Geology & Quaternary Geology, 2023, 43(5):136-147.]
|
[12] |
虞义勇, 王永红, 李日辉, 等. 渤海西部表层沉积物中黏土矿物分布特征及物源指示[J]. 海洋地质与第四纪地质, 2017, 37(1):51-58
YU Yiyong, WANG Yonghong, LI Rihui, et al. Clay Minerals Distribution Pattern in Surface Sediments of Western Bohai and Their Provenance Implications[J]. Marine Geology & Quaternary Geology, 2017, 37(1):51-58.]
|
[13] |
蓝先洪, 李日辉, 密蓓蓓, 等. 渤海东部和黄海北部表层沉积物稀土元素的分布特征与物源判别[J]. 地球科学, 2016, 41(3):463-474
LAN Xianhong, LI Rihui, MI Beibei, et al. Distribution Characteristics of Rare Earth Elements in Surface Sediment and Their Provenance Discrimination in the Eastern Bohai and Northern Yellow Seas[J]. Earth Science, 2016, 41(3):463-474.]
|
[14] |
王伟伟, 付元宾, 李树同, 等. 渤海中部表层沉积物分布特征与粒度分区[J]. 沉积学报, 2013, 31(3):478-485
WANG Weiwei, FU Yuanbin, LI Shutong, et al. Distribution on Surface Sediment and Sedimentary Divisions in the Middle Part of Bohai Sea[J]. Acta Sedimentologica Sinica, 2013, 31(3):478-485.]
|
[15] |
张剑, 李日辉, 王中波, 等. 渤海东部与黄海北部表层沉积物的粒度特征及其沉积环境[J]. 海洋地质与第四纪地质, 2016, 36(5):1-12
ZHANG Jian, LI Rihui, WANG Zhongbo, et al. Grain Size Characteristics of Surface Sediments in the Northern Yellow Sea and Their Implications for Environments[J]. Marine Geology & Quaternary Geology, 2016, 36(5):1-12.]
|
[16] |
Qin Y C, Mei X, Jiang X, et al. Sediment provenance and tidal current-driven recycling of Yellow River detritus in the Bohai Sea, China[J]. Marine Geology, 2021, 436:106473. doi: 10.1016/j.margeo.2021.106473
|
[17] |
王利波, 李军, 赵京涛, 等. 辽东湾表层沉积物碎屑矿物组合分布及其对物源和沉积物扩散的指示意义[J]. 海洋学报, 2014, 36(2):66-74
WANG Libo, LI Jun, ZHAO Jingtao, et al. Detrital mineral assemblages and distributions as indicators of provenance and dispersal pattern in surface sediments from Liaodong Bay, Bohai Sea[J]. Haiyang Xuebao, 2014, 36(2):66-74.]
|
[18] |
王伟, 李安春, 徐方建, 等. 北黄海表层沉积物粒度分布特征及其沉积环境分析[J]. 海洋与湖沼, 2009, 40(5):525-531 doi: 10.3321/j.issn:0029-814X.2009.05.001
WANG Wei, LI Anchun, XU Fangjian, et al. Distribution of Surface Sediments and Sedimentary Environment in the Northern Yellow Sea[J]. Oceanologia et Limnologia Sinica, 2009, 40(5):525-531.] doi: 10.3321/j.issn:0029-814X.2009.05.001
|
[19] |
窦衍光, 李军, 杨守业. 山东半岛东部海域表层沉积物元素组成及物源指示意义[J]. 海洋学报, 2012, 34(1):109-119
DOU Yanguang, LI Jun, YANG Shouye. Element compositions and provenance implication of surface sediments in offshore areas of the eastern Shandong Peninsula in China[J]. Haiyang Xuebao, 2012, 34(1):109-119.]
|
[20] |
密蓓蓓, 张勇, 梅西, 等. 南黄海表层沉积物稀土元素分布特征及其物源指示意义[J]. 海洋地质与第四纪地质, 2022, 42(6): 93-103
MI Beibei, ZHANG Yong, MEI Xi, et al. Distribution of rare earth elements in surface sediments of the South Yellow Sea and its implication to sediment provenances. Marine Geology & Quaternary Geology, 2022, 42(6): 93-103.
|
[21] |
Fang Y, Fang G, Zhang Q. Numerical simulation and dynamic study of the winter time circulation of the Bohai Sea[J]. Chinese Journal of Oceanology and Limnology, 2000, 18:1-9. doi: 10.1007/BF02842535
|
[22] |
Tian Z X, Zhang Y, Mei X, et al. Spatial distribution and ecological risk assessment of heavy metals in surface sediments from the northern Bohai Strait, China[J]. Environmental Monitoring and Assessment, 2022, 194:802. doi: 10.1007/s10661-022-10470-5
|
[23] |
王海根, 王庆同, 杨鹏, 等. 庙岛群岛西部海域表层沉积物常量和稀土元素的分布特征及其物源指示意义[J]. 海洋通报, 2023, 42(6): 695-706
WANG Haigen, WANG Qingtong, YANG Peng, et al. Distribution features of major elements and rare earth elements of the surface sediments in the western Miaodao Archipelago and their provenance implications. Marine Science Bulletin, 2023, 42(6): 695-706.
|
[24] |
中国科学院海洋研究所海洋地质研究室. 渤海地质[M]. 北京: 科学出版社, 1985
IOCAS (Institute of Oceanography, Chinese Academy of Sciences). Geology of the Bohai Sea[M]. Science Press, Beijing, 1985.]
|
[25] |
Yuan X, Feng X, Hu R, et al. Study on the sediment transport flux and mechanism in the Bohai strait at the tidal and monthly scales in summer[J]. Journal of Ocean University of China, 2023, 22(1):75-87.
|
[26] |
陈义兰, 吴永亭, 刘晓瑜, 等. 渤海海底地形特征[J]. 海洋科学进展, 2013, 31(1):75-82 doi: 10.3969/j.issn.1671-6647.2013.01.009
CHEN Yilan, WU Yongting, LIU Xiaoyu, et al. Features of Seafloor Topography in the Bohai Sea[J]. Advances in Marine Science, 2013, 31(1):75-82.] doi: 10.3969/j.issn.1671-6647.2013.01.009
|
[27] |
Mei X, Li R H, Zhang X H, et al. Evolution of the Yellow Sea Warm Current and the Yellow Sea Cold Water Mass since the Middle Pleistocene[J]. Paleogeography, Palaeoclimatology, Palaeoecology, 2016, 442:48-60. doi: 10.1016/j.palaeo.2015.11.018
|
[28] |
赵保仁, 庄国文, 曹德明, 等. 渤海的环流、潮余流及其对沉积物分布的影响[J]. 海洋与湖沼, 1995, 26(5):466-453 doi: 10.3321/j.issn:0029-814X.1995.05.003
ZHAO Baoyi, ZHUANG Guowen, CAO Deming, et al. Circulation, Tidal Residual Currents and Their Effects on the Sediments in the Bohai Sea[J]. Oceanologia et Limnologia Sinica, 1995, 26(5):466-453.] doi: 10.3321/j.issn:0029-814X.1995.05.003
|
[29] |
陆凯, 褚宏宪, 孙军, 等. 渤海海峡跨海通道地区海洋地质调查研究进展[J]. 地质通报, 2021, 40(Z1):287-297
LU Kai, CHU Hongxian, SUN Jun, et al. Research progress of marine geological survey of the Bohai Strait[J]. Geological Bulletin of China, 2021, 40(Z1):287-297.]
|
[30] |
Yang S, Jung H, Lim D, et al. A review on the provenance discrimination of sediments in the Yellow Sea[J]. Earth Science Review., 2003, 63(1-2):93-120. doi: 10.1016/S0012-8252(03)00033-3
|
[31] |
王金土. 黄海表层沉积物稀土元素地球化学[J]. 地球化学, 1990, 19(1):44-53 doi: 10.3321/j.issn:0379-1726.1990.01.005
WANG Jintu. REE geochemistry of surficial sediments from the Yellow Sea of China[J]. Geochimica, 1990, 19(1):44-53.] doi: 10.3321/j.issn:0379-1726.1990.01.005
|
[32] |
蓝先洪, 徐晓达, 王中波, 等. 渤海西部表层沉积物的稀土元素分布特征与物源约束[J]. 地球学报, 2018, 39(1):37-44 doi: 10.3975/cagsb.2017.111801
LAN Xianhong, XU Xiaoda, WANG Zhongbo, et al. Distribution Characteristics of Rare Earth Elements and Their Provenance Constraints in the Surface Sediments from the Western Bohai Sea[J]. Acta Geoscientica Sinica, 2018, 39(1):37-44.] doi: 10.3975/cagsb.2017.111801
|
[33] |
赵一阳, 王金土, 秦朝阳, 等. 中国大陆架海底沉积物中的稀土元素[J]. 沉积学报, 1990, 8(1):37-43
ZHAO Yiyang, WANG Jintu, QIN Zhaoyang, et al. Rare-Earth Elements in Continental Shelf Sediments of the China Seas[J]. Acta Sedimentologica Sinica, 1990, 8(1):37-43.]
|
[34] |
朱赖民, 高志友, 尹观, 等. 南海表层沉积物的稀土和微量元素的丰度及其空间变化[J]. 岩石学报, 2007, 23(11):2963-2980 doi: 10.3969/j.issn.1000-0569.2007.11.027
ZHU Laimin, GAO Zhiyou, YIN Guan, et al. Content and spatial change of rare earth element and trace element of surficial sediment in the South China Sea[J]. Acta Petrologica Sinica, 2007, 23(11):2963-2980.] doi: 10.3969/j.issn.1000-0569.2007.11.027
|
[35] |
Taylor S R, Mclennan S M. The continental crust: its composition and evolution[J]. The Journal of Geology, 1985, 94(4):57-72.
|
[36] |
古森昌, 陈绍谋, 吴必豪, 等. 南海表层沉积物稀土元素的地球化学[J]. 热带海洋学报, 1989, 2:93-101
GU Senchang, CHEN Shaomou, WU Bihao, etal. Geochemistry of Rare Earth Elements in Surface Sediments of the South China Sea[J]. Journal of Tropical Oceanography, 1989, 2:93-101.]
|
[37] |
张现荣, 李军, 窦衍光, 等. 辽东湾东南部海域柱状沉积物稀土元素地球化学特征与物源识别[J]. 沉积学报, 2014, 32(4):684-691
ZHANG Xianrong, LI Jun, DOU Yanguang, et al. REE Geochemical Characteristics and Provenance Discrimination of Core LDC30 in the Southeastern Part of Liaodong Bay[J]. Acta Sedimentologica Sinica, 2014, 32(4):684-691.]
|
[38] |
杨守业, 李从先. 长江与黄河沉积物REE地球化学及示踪作用[J]. 地球化学, 1999, 28(4): 374-380
YANG Shouye, LI Congxian. REE geochemistry and tracing applicationin the Yangtze River and the Yellow River sediments [J], Geochimica, 1999, 28(4): 374-380.]
|
[39] |
严杰, 高建华, 李军, 等. 鸭绿江河口及近岸地区稀土元素的物源指示意义[J]. 海洋地质与第四纪地质, 2010, 30(4):95-103
YAN Jie, GAO Jianhua, LI Jun, et al. The Source Indication Significance of Rare Earth Elements in the Yalu River Estuary and Nearshore Areas[J]. Marine Geology & Quaternary Geology, 2010, 30(4):95-103.]
|
[40] |
杨守业, 韦刚健, 夏小平, 等. 长江口晚新生代沉积物的物源研究: REE和Nd同位素制约[J]. 第四纪研究, 2007, 27(3):339-346 doi: 10.3321/j.issn:1001-7410.2007.03.005
YANG Shouye, WEI Gangjian, XIA Xiaoping, et al. Provenance Study of the Late Cenozoic Sediments in the Changjiang Delta: REE and ND Isotopic Constraints[J]. Quaternary Sciences, 2007, 27(3):339-346.] doi: 10.3321/j.issn:1001-7410.2007.03.005
|
[41] |
王庆同, 赵吉圆, 王海根, 等. 渤海海峡西南部海底沉积物重矿物组成与物源[J]. 海洋地质前沿, 2023, 39(6):22-31
WANG Qingtong, ZHAO Jiyuan, WANG Haigen, et al. Composition and provenance of heavy minerals in surface sediments in the southwestern Bohai Strait[J]. Marine Geology Frontiers, 2023, 39(6):22-31.]
|
[42] |
McLennan, S M. Weathering and Global Denudation[J]. The Journal of Geology, 1993, 101(2):295-303. doi: 10.1086/648222
|
[43] |
Tripathy G R, Singh S K, Ramaswamy V. M. Major and trace element geochemistry of Bay of Bengal sediments: implications to provenances and their controlling factors[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2014, 397(1):20-30.
|
[44] |
Zhu Y T, Bao R, Zhu L H, et al. Investigating the provenances and transport mechanisms of surface sediments in the offshore muddy area of Shandong Peninsula: Insights from REE analyses[J]. Journal of Marine Systems, 2022, 226:103671. doi: 10.1016/j.jmarsys.2021.103671
|
[45] |
徐方建, 李安春, 徐兆凯, 等. 东海内陆架沉积物稀土元素地球化学特征及物源意义[J]. 中国稀土学报, 2009, 27(4):574-582 doi: 10.3321/j.issn:1000-4343.2009.04.023
XU Fangjian, LI Anchun, XU Zhaokai, et al. Geochemical Characteristics and Source Significance of Rare Earth Elements in Sediments of the East China Sea Inland Shelf[J]. Journal of Rare Earths, 2009, 27(4):574-582.] doi: 10.3321/j.issn:1000-4343.2009.04.023
|
[46] |
黄龙, 耿威, 王中波, 等. 渤海东部和黄海北部表层有用重砂资源及影响因素[J]. 海洋地质前沿, 2016, 32(5):40-47
HUANG Long, GENG Wei, WANG Zhongbo, et al. Characteristics and Influence Factors of Valuable Heavy Minerals in Surface Sediments of the Eastern Bohai Sea and the Northern Yellow Sea[J]. Marine Geological Frontiers, 2016, 32(5):40-47.]
|
[47] |
袁萍. 渤海表层沉积物的空间分布及其与物源和沉积动力环境的关系[D]. 中国海洋大学硕士学位论文, 2015
YUAN Ping. Distribution of surface sediment in the Bohai Sea and its relationship with sediment supply and sedimentary dynamic environment[D]. Master Dissertation of Ocean University of China, 2015.]
|
[48] |
Kritsananuwat R, Sahoo S K, Fukushi M, et al. Distribution of rare earth elements, thorium and uranium in Gulf of Thailand’s sediments[J]. Environmental Earth Sciences, 2015, 73:3361-3374. doi: 10.1007/s12665-014-3624-8
|
[49] |
Xue C T, Qin Y C, Ye S Y, et al. Evolution of Holocene ebb-tidal clinoform off the Shandong Peninsula on East China Sea shelf[J]. Earth-Science Reviews, 2017, 17:478-496.
|
[50] |
李辉, 韩宗珠, 闫天浩, 等. 稀土元素配分曲线的相似性度量算法及其在黄海沉积物物源判别中的应用[J]. 海洋地质前沿, 2023, 39(12):88-97
LI Hui, HAN Zongzhu, YAN Tianhao, et al. Similarity measurement algorithm of REE distribution curve and its application for provenance discrimination of sediments in the Yellow Sea[J]. Marine Geology Frontiers, 2023, 39(12):88-97.]
|