ZENG Zhigang，CHEN Zuxing，QI Haiyan，et al. Chemical and sulfur isotopic compositions of anhydrite from the Tangyin hydrothermal field in the Okinawa Trough[J]. Marine Geology & Quaternary Geology，2023，43(5)：1-16. DOI: 10.16562/j.cnki.0256-1492.2023060601
Citation: ZENG Zhigang，CHEN Zuxing，QI Haiyan，et al. Chemical and sulfur isotopic compositions of anhydrite from the Tangyin hydrothermal field in the Okinawa Trough[J]. Marine Geology & Quaternary Geology，2023，43(5)：1-16. DOI: 10.16562/j.cnki.0256-1492.2023060601
shu

Chemical and sulfur isotopic compositions of anhydrite from the Tangyin hydrothermal field in the Okinawa Trough

  • 1.

    Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China

  • 2.

    Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China

  • 3.

    Laboratory for Marine Mineral Resources, Laoshan Laboratory, Qingdao 266237, China

  • 4.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • 5.

    Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, China

More Information
  • Received Date: June 05, 2023
  • Revised Date: July 26, 2023
  • Available Online: October 29, 2023
    Graphical Abstract
    • Abstract
  • Anhydrite is one of the earliest minerals in forming the hydrothermal chimney walls, which is important for understanding the fluid-seawater mixing, and elemental migration and cycling in the seafloor hydrothermal system. Anhydrite minerals samples from the Tangyin hydrothermal field in the southwestern Okinawa Trough, western Pacific were investigated on the in-situ element concentrations and sulfur (S) isotopic compositions. The crystal morphology of anhydrite could be divided into two types. Type I anhydrite formed earlier is subhedral or anhedral and occurred in radial or irregular crystal aggregation, and Type II anhydrite formed later is euhedral and occurred in plate or granular crystal aggregation. When the hydrothermal fluid first met with seawater, Type I anhydrite precipitated rapidly and formed the wall of the hydrothermal chimney. Subsequently, Type II anhydrite experienced relatively longer growth stage. However, the Ba, Al, Sr, Ni, Fe, Mn, and Cr contents of anhydrite are significantly higher than that of seawater, suggesting that those elements are derived mainly from hydrothermal fluid duo to the subseafloor fluid-rock and/or sediment interactions. The Mg content of anhydrite is significantly lower / higher than that of seawater / vent fluids, which was resulted from the fluid-seawater mixing. Most of the Sr contents of Type I anhydrite are significantly lower than that of Type II anhydrite, suggesting that more Sr from fluids were involved into Type II anhydrite and formed euhedral, plate, or granular minerals. The Fe, As, Sr, Ba, and Pb contents of anhydrite are significantly higher than that of vent fluids in the Okinawa Trough, which indicates that these elements enter preferentially anhydrite from the fluids, and resulted in the enrichment of these elements in the anhydrite. REEs of anhydrite and their REE patterns show positive Ce and negative Eu anomalies, which could be resulted from fluids leaching out from local sub-seafloor volcanic rocks and/or sediments and having undergone fluid-seawater mixing. Furthermore, S in the anhydrite was mainly from seawater during fluid-seawater mixing.
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