OXYGEN ISOTOPE OF QUARTZ IN SEDIMENTS FROM THE YANGTZE (CHANGJIANG) AND YELLOW(HUANGHE) RIVERS
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摘要: 采用硫酸氢钾(KHSO4)熔融-六氟硅酸(H2SiF6)浸泡的化学方法分离出长江、黄河河口不同粒级沉积物中的石英矿物,使用BrF5为氧化剂提取出石英矿物中的氧,在质谱计上测定石英中氧同位素比值(δ18O值),结果表明:同一沉积物样品中随粒度由粗变细,石英δ18O值逐渐增加,长江河口沉积物中石英的δ18O值比黄河河口沉积物中的稍高,两条河流河口沉积物中相同粒级石英δ18O值差别主要受流域沉积物物质来源和流域的气候环境差异的影响。Abstract: Quartz in sediments from the Yangtze and Yellow Rivers was separated by potassium hydrogen sulfate (KHSO4) fusing-hydrofluorosilic acid (H2SiF6). Oxygen was extracted from the quartz fraction by BrF5 (used as oxidant), and then its isotopic composition was analyzed by mass-spectrometer, expressed as δ18O (18O/16O)values (relative to SMOW). The results show that δ18O values generally increase with grain size of quartz changing from coarse to fine. The oxygen isotope ratios (δ18O) of quartz from the Yangtze River are higher than those from the Yellow River. The differences in δ18O values of the same grain-size quartz between the Yangtze and Yellow Rivers may have resulted from different sediment sources and climate conditions along these two river basins.
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Keywords:
- quartz /
- sediment /
- oxygen isotope ratio /
- the Yangtze River /
- the Yellow River
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[1] 汤奇成,熊怡.中国河流水文[M].北京:科学出版社,1998:127-153.[TANG Qi-cheng, XIONG Yi. Hydrological Characteristics of Rivers in China[M]. Beijing:Science Press,1998:127 -153.]
[2] 任美锷.任美锷地理论文选[M].北京:商务印书馆,1991:368-385.[REN Mei-e. REN Mei-e's Thesis about Geography[M]. Beijing:The Commercial Press, 1991:368 -385.]
[3] Kiely P V, Jackson M L. Quartz, feldspar, and mica determination for soils by sodium pyrosulfate fusion[J]. Soil Sci. Amer. Pro., 1965, 29:159-163.
[4] Clayton R N, Jackson M L, Sridhar K. Resistance of quartz silt to isotopic exchange under burial and intense weathering conditions[J]. Geochim. Cosmochim. Acta.,1978,42:1517-1522.
[5] Jackson M L. Oxygen isotope ratios in quartz as an indicator of provenance of dust[J]. Geological Society of America-Special Paper, 1981, 186:27-36.
[6] Aléon Jérôme, Chaussidon Marc, Marty Bernard, et al. Oxygen isotopes in single micrometer-sized quartz grains:tracing the source of Saharan dust over long-distance atmospheric transport[J]. Geochimica et Cosmochimica Acta, 2002, 66(19):3351-3365.
[7] GU Zhao-yan, LIU Tung-sheng, ZHENG Shu-hui. A preliminary study on quartz isotope in Chinese loess and soil[C]//Aspects of Loess Research. Beijing:China Ocean Press, 1987:291-301.
[8] Mizota C, Matsuhisa Y. Isotopic evidence for the eolian origin of quartz and mica in soils developed on volcanic materials in the Canary Archipelago[J]. Geoderma, 1995, 66:313-320.
[9] Mizota C, Faure K, Yamamoto M. Provenance of quartz in sedimentary mantles and laterites overlying bedrock in West Africa:evidence from oxygen isotopes[J]. Geoderma, 1996,72:65-74.
[10] Xiao J L, Yoshio Inouchi, Liu Tungsheng. Eolian quartz flux to Lake Biw, central Japan, over the past 145000 years[J]. Quaternary Research, 1997, 48:48-57.
[11] 侯圣山,杨石岭,丁仲礼.风成沉积物4~16μm石英氧同位素记录及其物质来源意义[J].中国科学D辑,2003,33(6):535-542. [HOU Sheng-shan, YANG Shi-ling, DING Zhong-li. Oxygen isotope compositions of quartz grains (4~16μm) from Chinese eolian deposits and their implications for provenance[J]. Science in China (Series D), 2003, 33(6):535-542.]
[12] 中华人民共和国国家标准(GB/T 13909-92)[S]. 海洋调查规范:海洋地质地球物理调查.北京:国家技术监督局,1992:11-28.[GB/T 13909-92 [S]. Specification for oceanographic survey-Marine geology and geophysics investigation. Beijing:1992:11-28.]
[13] 万世明,蒋恒毅,李安春.海洋沉积物中石英单矿物的化学分离[J].海洋地质与第四纪地质,2003,23(3):123-127. [WAN Shi-ming, JIANG Heng-yi, LI An-chun. Chemical separation of quartz from marine sediment samples[J]. Marine Geology and Quaternary Geology, 2003, 23(3):123-127.]
[14] 孙有斌.黄土样中石英单矿物的分离[J].岩矿测试,2001,20(1):23-26. [SUN You-bin. Separation of quartz minerals from loess samples[J]. Rock and Mineral Analysis, 2001, 20(1):23-26.]
[15] 李延河,万德芳,张国柄,等.氧化物、硅酸盐矿物的氧同位素分析方法-BrF5法[C]//稳定同位素分析方法研究进展.北京:科学技术出版社,1992:37-43.[LI Yan-he, WAN De-fang, ZHANG Guo-bing, et al. An analysis method of oxygen isotope in oxide and silicates -BrF5 method[C]//Advance in Analysis Methods of Stable Isotopes. Beijing:Science Press, 1992 :37-43.]
[16] YANG Shou-ye, JUNG Hoi-Soo, LI Cong-xian. Two unique weathering regimes in the Changjiang and Huanghe drainage basins:geochemical evidence from river sediments[J]. Sedimentary Geology, 2004, 169:19-34.
[17] CHEN Jing-sheng, WANG Fei-yue, XIA Xing-hui, et al. Major element chemistry of the Changjiang (Yangtze River)[J]. Chemical Geology, 2002, 187:231-255.
[18] REN Mei-e, SHI Yun-liang. Sediment discharge of the Yellow River (China) and its effect on the sedimentation of the Bohai and the Yellow Sea[J]. Cont. Shelf Res., 1986, 6:785-810.
[19] 孙继敏.中国黄土的物质来源及其粉尘的产生机制与搬运过程[J].第四纪研究,2004,24(2):175-183. [SUN Ji-min. Provenance, forming mechanism and transport of loess in China[J]. Quaternary Sciences, 2004, 24(2):175-183.]
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