东菲律宾海深水区新型铁锰结壳的特征和成因

徐兆凯; 李安春; 蒋富清; 孟庆勇; 刘建国

东菲律宾海深水区新型铁锰结壳的特征和成因

1 中国科学院海洋地质与环境重点实验室, 中国科学院海洋研究所, 青岛 266071;
2 中国科学院研究生院, 北京 100039

基金项目:

国家自然科学基金项目(40576032,40506016)

中国科学院知识创新工程重要方向项目(KZCX3-SW-223)

详细信息

作者简介:
徐兆凯(1978-),男,博士生,主要从事海洋沉积和矿物学研究,E-mail:xuzhaokai@ms.qdio.ac.cn

中图分类号: P744.3
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出版历程
- 收稿日期: 2006-02-07
- 修回日期: 2006-05-16

CHARACTERISTICS AND ORIGIN OF THE NEW-TYPE FERROMANGANESE CRUSTS FROM DEEPWATER AREAS OF THE EAST PHILIPPINE SEA

1 Key Laboratory of Marine Geology and Environment of Chinese Academy of Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;
2 Graduate School of Chinese Academy of Sciences, Beijing 100039, China

摘要

摘要: 对取自东菲律宾海深水区致密-半固结沉积物表层的新型铁锰结壳典型样品进行了X射线衍射、X射线荧光、电感耦合等离子体原子发射光谱及加速器质谱研究。结壳的组成矿物主要有δMnO₂、铁的氧化物/氢氧化物、石英、长石和黏土矿物等。与海山结壳相比,其Mn、Co、Ni、Zn、Pb含量均较低,而Fe、Cu、Al含量则相对较高。Mn/Fe值平均仅为0.24,也低于海山结壳Mn/Fe的平均值。相关性分析、元素分配系数分析及稀土元素北美页岩标准化配分模式等结果均表明,研究区结壳为一新型边缘海深水水成结壳,与海山水成结壳间存在一定差异。结壳的物质组分主要来自于同期海水,同时碎屑物质对其形成也有一定贡献;并且它们自形成以来没有遭受明显的成岩后期改造和元素再迁移,具有较高的古海洋学应用价值。
- 新型铁锰结壳 /
- 地球化学特征 /
- 成因 /
- 东菲律宾海
Abstract: XRD, XRF, ICP-OES and ICP-MS analyses were carried out on typical new-type ferromanganese crusts sampled on the surface of compact to half-solid sediment from deepwater areas of the East Philippine Sea. The crusts are mainly composed of δMnO₂, FeOOH·nH₂O, quartz, feldspar, clay minerals and so on. Compared to seamount crusts, their Mn, Co, Ni, Zn and Pb content is lower, whereas the abundance of Fe, Cu and Al is higher. The average of Mn/Fe ratios is only 0.24, which is also lower than that of seamount crusts. Analysis results of interelemental association, elemental distribution coefficient and REE NASC-normalized pattern all indicate that the studied crusts are new-type deepwater ferromanganese crusts in the margin sea, which are somewhat different from seamount crusts. Sources of new-type crusts mainly come from homochronous seawater and the detrital materials also make some contribution. Having not been influenced by significant post-depositional reconstruction and remobilization of elements, the new-type crusts have important paleoceanographic application value.
- new-type ferromanganese crust /
- geochemical characteristics /
- origin /
- East Philippine Sea

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参考文献(23)

[1]	王毅民. 深海矿产资源研究开发中的分析技术[J]. 岩矿测试, 1992, 11(1/2):179. [WANG Yi-min. Analysis technology in the research and development of deep-sea mine resource[J]. Rock and Mineral Analysis, 1992, 11(1/2):179.]
[2]	Hein J R, Schwab W C, Davis A S. Cobalt and platinum-rich ferromanganese crusts and associated substrate rocks from the Marshall Islands[J]. Marine Geology, 1988, 78:255-283.
[3]	潘家华, 刘淑琴. 大洋固体矿产富钴锰结壳研究进展[C]//当代地质科学技术进展. 武汉:中国地质大学出版社, 1995:16-23.[PAN Jia-hua, LIU Shu-qin. Research progress of Co-rich Mn crusts as an ocean solid mine[A]. CHENG En-hua. Recent progress of geological science and technology[C]. Wuhan:China University of Geosciences Press, 1995:16 -23.]
[4]	蔡毅华, 黄奕普. 富钴结壳地球化学与古海洋学研究进展[J]. 台湾海峡, 2002, 21(2):258-264. [CAI Yi-hua, HUANG Yi-pu. Advance on studies of geochemistry and paleoceanography of the Co-rich crust[J]. Journal of Oceanography in Taiwan Strait, 2002, 21(2):258-264.]
[5]	陈穗田, Stüben D. 菲律宾海的锰结壳和锰结核[J]. 海洋学报, 1997, 19(4):109-116. [CHEN Sui-tian, Stüben D. Ferromanganese crusts and nodules of the Philippine Sea[J]. Acta Oceanologica Sinica, 1997, 19(4):109-116.]
[6]	Scott R B, Kroenke L, Zakariadze G. Evolution of the south Philippine Sea:Deep Sea Drilling Project Leg 59 results[C]//Kroenke L, Scott R B, Brassell S, et al. Initial Reports of the Deep Sea Drilling Project, V59. U.S. Govt. Printing Office, 1981:803-815.
[7]	Ujiie H. Planktonic foraminiferal biostratigraphy in the Western Philippine Sea, Leg 31 of DSDP[C]//Karig D E, Ingle J C Jr, et al. Initial Reports of the Deep Sea Drilling Project, Leg 31. U.S. Govt. Printing Office, 1975:677-691.
[8]	赵澄林. 沉积学原理[M]. 北京:石油工业出版社, 2001:96.[ZHAO Cheng-lin. Sedimentary Theory[M]. Beijing:Petroleum Industry Press, 2001:96.]
[9]	朱而勤. 近代海洋地质学[M]. 青岛:青岛海洋大学出版社, 1991:320-328.[ZHU Er-qin. Neoteric Marine Geology[M]. Qingdao:Qingdao Ocean University Press, 1991:320 -328.]
[10]	Koschinsky A, Halbach P. Sequential leaching of marine ferromanganese precipitates:Genetic implications[J]. Geochimica et Cosmochimica Acta, 1995, 59:5113-5132.
[11]	梁宏锋, 许东禹, 林振宏, 等. 太平洋几个不同海区水成铁锰结壳元素地球化学研究[C]//多金属结核形成的古海洋环境. 北京:地质出版社, 1994:22-41.[LIANG Hong-feng, XU Dong-yu, LIN Zhen-hong, et al. Element geochemistry of hydrogenic ferromanganese crusts from some areas in the Pacific Ocean[C]//Formative Paleo Ceanographic Conditions of the Polymetallic Nodules. Beijing:Geological Publishing House, 1994:22 -41.]
[12]	De Carlo E H, Fraley C M. Chemistry and mineralogy of ferromanganese deposits from the South Equatorial Pacific Ocean[C]//Bolton B, Keating B. Geology and Offshore Mineral Resources of the Central Pacific Basin. Circum-Pacific Council for Energy and Mineral Resources, Earth Sci. Series Volume 14. Houston, TX, 1992:225-245.
[13]	Wen X, De Carlo E H, Li Y H. Interelement relationships in ferromanganese crusts from the central Pacific Ocean:Their implications for crust genesis[J]. Marine Geology, 1997, 136:277-297.
[14]	Banakar V K, Pattan J N, Mudholkar A V. Palaeoceanographic conditions during the formation of a ferromanganese curst from the Afanasiy-Nikitin seamount, North Central Indian Ocean:geochemical evidence[J]. Marine Geology, 1997, 136:299-315.
[15]	De Carlo E H, McMurtry G M. Rare earth element geochemistry of Fe-Mn deposits from the Hawaiian Archipelago[J]. Chemical Geology, 1992, 95:235-250.
[16]	Piper D Z. Rare earth elements in the sedimentary cycle:a summary[J]. Chemical Geology, 1974, 14:285-304.
[17]	Greaves M J, Elderfield H, Sholkovitz E R. Aeolian sources of rare earth elements to the Western Pacific Ocean[J]. Marine Chemistry, 1999, 68:31-38.
[18]	刘英俊, 曹励明. 元素地球化学导论[M]. 北京:地质出版社, 1987:57-80.[LIU Ying-jun, CAO Li-ming. General Element Geochemistry[M]. Beijing:Geological Publishing House, 1987:57 -80.]
[19]	韩吟文, 马振东. 地球化学[M]. 北京:地质出版社, 2003:37.[HAN Yin-wen, MA Zhen-dong. Geochemistry[M]. Beijing:Geological Publishing House, 2003:37.]
[20]	Hussong D M, Uyeda S. Tectonic process and the history of the Marina Arc:a synthesis of the results of Deep Sea Drilling Project Leg 60[C]//Hussong D M, Uyeda S, Jr, et al. Initial Reports of the Deep Sea Drilling Project, V60. U.S. Govt. Printing Office, 1982:909-929.
[21]	Katherine M B. Cenozoic clay-mineral stratigraphy in the South Philippine Sea[C]//Kroenke L, Scott R B, Brassell S, et al. Initial Reports of the Deep Sea Drilling Project, V59. U.S. Govt. Printing Office, 1981:597-602.
[22]	Kolla V, Nadler L, Bonatti E. Clay mineral distributions in surface sediments of the Philippine Sea[J]. Oceanologica Acta, 1980, 3(2):245-250.
[23]	孙守勋, 滕军. 菲律宾海的气候特征[J]. 海洋预报, 2003, 20(3):31-39. [SUN Shou-xun, TENG Jun. Climate character of the Philippine Sea[J]. Marine Forecasts, 2003, 20(3):31-39.]